In a shallow bowl, combine the brown sugar, smoked paprika, sea salt, ground mustard, onion powder, black pepper, garlic powder, and cayenne if you're using it. Stir them together with a fork, breaking up any lumps in the brown sugar. This matters because lumps won't distribute evenly, leaving you with pockets of concentrated sweetness and bare spots on your meat.
I like to smell the mixture at this point — it's a tiny ritual that reminds me why I love cooking. That aroma tells you whether your spices are fresh and alive. If something smells flat or muted, that's your signal to replace it before your next cook.